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=TotalMTotal%OO>Warning Text?Warning Text%XTableStyleMedium9PivotStyleLight16`Sheet1 h)Table 6A Source Area BTEX and VPH Datapassword = example?NAPL Contaminated Soil Source Area Hydrocarbon CharacterizationSample Location /FacilityBoring or Well NumberSample Starting Depth (ft)
Sampling DateSample NameBenzeneTolueneEthylbenzeneXylene (total)C8C10 AromaticsC9C10 AromaticsC10C12 AromaticsC12C13 AromaticsC5C6 AliphaticsC6C8 AliphaticsC8C10 AliphaticsC10C12 Aliphatics Total VPH2GRO (calculated as sum of C5 to C10 A&A)
(mg/kg)) GRO by AK101 (Stat Value, mg/kg) DRO by AK102 (Stat Value, mg/kg) RRO by AK103 (Stat Value, mg/kg)% GRO% DRO% RROLab Result (mg/kg)Method Detection Limit (mg/kg)Stat Value (mg/kg)Calculated Value (mg/kg)%average concentration within fractionP"ND" results are assumed to be the following fraction of the detection limit: "Table 6B Source Area EPH DataC12C16 AromaticsC16C21 AromaticsC21C34 AromaticsC12C16 AliphaticsC16C21 AliphaticsC21C34 Aliphatics!DRO Aromatics C10 to C21 (mg/kg) "DRO Aliphatics C10 to C21 (mg/kg) #DRO (Sum of C10 to C21 A&A) (mg/kg)$RRO (sum of C21 to C34 A&A) (mg/kg),Sum of all EPH Fractions Stat Values (mg/kg)*Extractable Petroleum Hydrocarbons (mg/kg)Notes:1A&A EC = aliphatic and aromatic equivalent carbon6Table 6C Source Area Hydrocarbon CharacterizationThis spreadsheet has been developed to help HRC users calculate 1) the soil GRO, DRO and RRO aromatic fractions, which are input values in cells C14 to C16 of the HRC; and 2) the equivalent carbon mass fractions within the GRO aliphatic, DRO aromatic, and DRO aliphatic groups, which are input values to cells D75 to D77 and D79 to D84 of the HRC. The table number, title and data in this spreadsheet are presented as an example and should be changed by the user so that the data becomes specific to their site. Compounds and A&A EC FractionsBTEXTPHEnter the BTEX, EPH and VPH concentration data from the more heavily contaminated portions of the source area (sample results with GRO concentrations above 300 and DRO or RRO concentrations above 250 mg/kg) into the unshaded cells in Tables 6A and 6B (it is best if the lab results are reported to the detection limit and estimated or "J" results are used when they occur). The BTEX data should come from the same sample as the VPH and EPH data, and should be from the 8021 or 8260 test methods (don't use the BTEX values produced by the VPH test method). If a lab result is nondetect, enter "ND" into the "Lab Result" column of Table 6A and/or 6B. By default the spreadsheet assigns a "statistical value" equal to the method detection limit to all nondetect concentration data (the fraction of the detection limit used in the statistical value calculation may be adjusted by changing cell H18) . The values needed by the HRC will be calculated automatically and displayed in Table 6D. aSource of data used as input to the characterization were overlap exists (enter: max, VPH or EPH)VPHEPH.Average concentration in A&A EC groups (mg/kg)=The spreadsheet calculates the average concentration value within each A&A EC fraction (e.g., C8 C10 aromatics) as shown in the gray highlighted lines of Table 6A and 6B. The spreadsheet pulls the average concentrations in each A&A EC fraction from the VPH and EPH data into a summary table (line 3 of Table 6C). %Fraction of TPH mass in A&A EC groupsFor A&A EC fractions measured by both the VPH and EPH methods, the spreadsheet, by default, selects the higher of the two overlapping average concentrations (if cells I45, J45, P45 and O45 are left blank). If the user has reason to believe that the either the VPH or EPH result of the overlapping ranges is a more representative value, then that value may be selected by entering "VPH" or "EPH" in the light yellow cells in line 2 of Table 6C (rational for the selection must be supplied in the report). In general, the VPH data is thought to be more representative of the C9C10 fractions and the EPH data is thought to be more representative of the C10C12 fractions (but the laboratory QA/QC data, and the correlation of the GRO and DRO data from the AK101 and AK102 tests with the VPH and EPH data may be used to help assess whether the VPH or EPH data is used as input to the hydrocarbon characterization). GRO, DRO & RRO A&A Groups
GRO aromatics
DRO aromatics
RRO aromaticsGRO aliphaticsDRO aliphaticsRRO aliphatics>Sum of A&A EC mass fractions within GRO, DRO & RRO A&A Groups \The concentrations within the A&A EC fractions are added to get a total petroleum hydrocarbon (TPH) concentration (cell V40). Then the mass fraction within each A&A EC fraction is calculated by dividing the average concentration within the fraction by the TPH concentration as shown in the row labeled Fraction of TPH mass within A&A EC groups . ?Mass fraction of A&A EC Groups within GRO, DRO & RRO A&A Groups
The spreadsheet calculates the mass fraction of each A&A EC group within the larger GRO aliphatic, DRO aromatic and DRO aliphatic groups by dividing the mass fraction of each A&A EC group within the TPH, by the sum of the mass fractions within the larger GRO aliphatic, DRO aromatic and DRO aliphatic groups (as shown lines 6 and 7 of Table 6C) . These values are inputs for cells D75 to D77 and cells D79 to D84 of the HRC and are shown in Table 6D in a format where they can be readily copied and pasted into the HRC. =Sum of A&A EC mass fractions within GRO, DRO & RRO A&A Groups The GRO, DRO and RRO aromatic fractions are calculated (e.g. the sum of the GRO aromatic mass fractions divided by the sum of the GRO aromatic and aliphatic mass fractions) and are shown in Table 6D in a format where they can be readily copied and pasted into cells C14 to C16 of the HRC.sNote that the fractions used as input to cells D75 to D77, D79 to D81 and D82 to D84 must total to 1. Therefore it is recommended that the values in Table 6D be copied and pasted into the HRC (rather than manually entered into the HRC). When pasting the Table 6D values into the HRC use the "paste special values" option so that the formatting of the HRC is preserved. >The user can add rows the middle of Table 6B and 6B as needed.Please enter the GRO, DRO and RRO concentration measured by the AK101, AK102 and AK103 test methods in columns AR throught AT. The concentrations and percentages of GRO, DRO and RRO in the samples maybe used to help assess if the sample is from a source area and whether the source is associated with a gasoline, diesel or lube oil/waste oil release. If GRO, DRO, RRO, VPH and EPH data indicate significantly different hydrocarbon character (for example some of the source area samples show >90% DRO and <10% RRO while others show ~75% RRO and only ~25% DRO then a waste oil or lube oil spill is indicated and the source may be subdivdied into two separate source areas a diesel source area and a waste oil source area. Table 6D: HRC Input<input to cells C14 to C16
(4phase, cumulative risk calcs) ;input to cells D75 to D77
(4phase, cumulative risk calcs);input to cells D79 to D84
(4phase, cumulative risk calcs)GRO: fraction aromatic DRO: fraction aromaticAromatic C10C12
Aliphatic C5C6
RRO: fraction aromaticAromatic C12C16
Aliphatic C6C8
Aromatic C16C21
Aliphatic C8C10
<DAliphatic C10C12
Aliphatic C12C16
Aliphatic C16C21
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